BPMHM - E-180, 2-ETHOXYETHANOL
- MSDS: BPMHM
- Manufacturer: FISHER SCIENTIFIC
- Product Name: E-180, 2-ETHOXYETHANOL
- National Stock Number: 6810-00-836-8638
Product Identification
Product ID:E-180, 2-ETHOXYETHANOL
MSDS Date:06/29/1988
FSC:6810
NIIN:00-836-8638
MSDS Number: BPMHM
Responsible Party
FAIR LAWN, NJ 07410-2802
US
Emergency Phone: 201-796-7100
Info Phone: 201-796-7100
Cage: 1B464
Contractor
Telephone: 201-796-7100
Cage: 1B464
Ingredients
ETHANOL, 2-ETHOXY-; (2-ETHOXYETHANOL) (EGEE) (SARA III)
CAS: 110-80-5
RTECS: KK8050000
Fraction By Weight: >99%
OSHA PEL 200 PPM, S
ACGIH TLV: 5 PPM, S
EPA Report Quantity: 1000 LBS
DOT Report Quantity: 1000 LBS
WATER
CAS: 7732-18-5
RTECS: ZC0110000
Fraction By Weight: <1%
BREATHING VAPORS, KEEP UPWIND.
RTECS: 9999999ZZ
BEEN SLIGHT YELLOWISH DISCOLORATION OF
RTECS: 9999999ZZ
LEV OF BILIRUBIN IN BLOOD OF ANOTHER. ANIMALS EXPOS
RTECS: 9999999ZZ
ON PREG RATS
RTECS: 9999999ZZ
RAT FEEDING STUDY DECREASED
RTECS: 9999999ZZ
LESIONS IN LIVER/KIDNEYS, TESTICULAR ATROPHY,FETAL
RTECS: 9999999ZZ
INJ.EYE/MUC MEMB IRRIT.POIS MAY AFFECT
RTECS: 9999999ZZ
WORKPLACE AS HAVING POTNTL TO CAUSE ADVERSE REPROD
RTECS: 9999999ZZ
APPEARS ON NAVY LISTING OF OCCUP REPROD HAZ. SEEK
RTECS: 9999999ZZ
LATEST HAZARD LIST INFORMATION AND SAFE HANDLING
RTECS: 9999999ZZ
IF VICTIM IS
RTECS: 9999999ZZ
BY TOUCHING FINGER TO BACK OF THROAT. GET MED ATTN
RTECS: 9999999ZZ
BY QUALIFIED MEDICAL PERSON ONLY (SEE OTHER
RTECS: 9999999ZZ
IF H*2O POLLUTION OCCURS, NOTIFY APPROP AUTH.
RTECS: 9999999ZZ
ABSORB SPILLED MATL W/ACTIVATED CARBON. OCCUP
RTECS: 9999999ZZ
TAKE UP
RTECS: 9999999ZZ
DIKE FAR AHEAD OF SPILL FOR LATER
RTECS: 9999999ZZ
PEOPLE AWAY; ISOLATE AND DENY ENTRY.
RTECS: 9999999ZZ
TO MAINTAIN NORMAL SERUM CALCIUM LEVS.CALCIUM
RTECS: 9999999ZZ
OXALATE IN KIDNEY. (DREISBACK, HANDBOOK OF
RTECS: 9999999ZZ
QUALIFIED MEDICAL PERSONNEL ONLY.
RTECS: 9999999ZZ
PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
RTECS: 9999999ZZ
Hazards
LD50 LC50 Mixture:LD50: (ORAL,RAT) 3000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:(ACUTE)INHAL: IRRIT & DISAGREEABLE IN
TOX CONC. SKIN: SYS EFTS HAVE NOT BEEN REPORTED. EYE: IMMED PAIN,
SOME CONJUNCTIVAL IRRIT & SLIGHT TRANSIENT IRRIT OF CORNEA WHICH
CLEARS W/IN 24 HRS. VAP CAN CAU SE IRRIT. INGEST: ANIMAL STUDIES
SHOW REVERSIBLE LIVER/KIDNEY INJ, DYSPNEA, CRAMPS, HEMORR, LIVER
INJ, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: KIDNEY INJ, GEN ANESTH, DEATH. ONE
HUMAN CASE CAUSED VERTIGO, RAPIDLY FOLLOWED BY UNCON, CYANOTIC,
TACHYPNEA, PULM EDEMA, RPTD TONIC-CLONIC SPASMS & AN ACETONE ODOR
ON BRTH. O*2 & OTHER SUUP ORTIVE TREATMENT RSLTD IN ESSENTIALLY
COMPLETE RECOVERY. (CHRONIC)INHAL: ONLY REPORTED SYS EFTS IN HUMANS
HAVE (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
First Aid
First Aid:INHAL: REMOVE FROM EXPOS TO FRESH AIR IMMED.IF BRTHG STOPPED,
PERFORM ARTF RESP. KEEP PERSON WARM & AT REST.GET MD IMMED. SKIN:
REMOVE CONTAM CLTHG/SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD
DETERGEN T & LRG AMTS OF H*2O UNTIL NO CHEM REMAINS (15-20 MIN).
GET MED ATTN IMMED. EYE: WASH EYES IMMED W/LRG AMTS OF H*2O FOR AT
LEAST 15 MIN, OCCAS LIFTING UPPER/LOWER LIDS, UNTIL NO CHEM
REMAINS. (ING 13)
Fire Fighting
Flash Point Method:CC
Flash Point:110F,43C
Lower Limits:1.7% @ 200F
Upper Limits:15.6% @ 200F
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
ALCOHOL FOAM. FOR LRGR FIRES, USE H*2O SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.MOVE CNTNR FROM FIRE AREA IF POSS.COOL FIRE-EXPOS CNTNRS
W/H*2O FROM SIDE UNTIL WELL AFTER FIRE IS (SUPDAT)
Unusual Fire/Explosion Hazard:VAPOR-AIR MIX EXPLOSIVE ABOVE FLASH
POINT. VAPORS HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE
TO SOURCE OF IGNITION AND FLASH BACK.
Accidental Release
Spill Release Procedures:RUN-OFF TO SEWER MAY CREATE FIRE/EXPLO
HAZ.SOIL SPILL: DIG HOLDING AREA SUCH AS PIT, POND/LAGOON TO
CONTAIN SPILL & DIKE SURF FLOW USING BARRIER OF SOIL, SANDBAGS,
FOAMED POLYURETHANE/FOAMED CONCRETE. ABSORB LIQ MASS W/FLY
ASH/CEMENT POWDER. (ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
Handling
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NOTE TO MD:ANTIDOTE: GIVE 50% ETHANOL,1.5
ML/KG,ORALLY INITIALLY, DILUTED TO NOT >5% SOLN,FOLLOWED BY 0.5-1.0
ML/KG EVERY 2 HRS ORALLY/IV FOR 4 DAYS.GIVE CALCIUM GLUCONATE,10 ML
OF 10% SOLN DILUTED IN 1 LITER OF 5% GLUCOSE,IV AS NEC(ING 21)
Exposure Controls
Respiratory Protection:ANY NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE &
OPER IN PRESS-DEMAND/OTHER POS PRESS MODE. ANY NIOSH/MSHA APPRVD
SUPPLIED-AIR RESP W/FULL FACEPIECE & OPER IN PRESS-DEMAND/OTHER POS
PRESS MODE IN COMBINA TION W/AUXILIARY SCBA OPER IN (ING 24)
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION
VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:PROT CLTHG TO PVNT ANY POSS OF CONT. EYE
WASH FOUNTAIN & QUICK DRENCH SHOWER W/IN IMMED WORK AREA FOR
EMERGENCY.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: OUT. STAY AWAY FROM STORAGE TANK ENDS. FOR MASSIVE
FIRE, USE UNMANNED HOSE HOLDER, ELSE LET FIRE BURN. WITHDRAW IMMED
IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE/ANY DISCOLORAT
ION OF STORAGE TANK. USE H*2O AS FOG, SOLID STREAMS MAY BE INEFT.
COOL CNTNRS FROM AS FAR A DIST AS POSS. AVOID (ING 3)
Chemical Properties
Boiling Pt:B.P. Text:275F,135C
Melt/Freeze Pt:M.P/F.P Text:-94F,-70C
Vapor Pres:3.8 @ 68F
Vapor Density:3.0
Spec Gravity:0.93
Evaporation Rate & Reference:0.32 (BU ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:PRACTICALLY ODORLESS, COLORLESS LIQUID. SLIGHTLY
BITTER.
Stability
Stability Indicator/Materials to Avoid:YES
ALUMINUM, OXIDIZERS, ACIDS AND ALKALIS, PLASTICS, RUBBERS, COATINGS,
MAGNESIUM, GALVANIZED METALS, ZINC.
Stability Condition to Avoid:HEAT, SPARKS, OR FLAMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCES TOXIC
VAPORS AND GASES, INCLUDING CARBON MONOXIDE. MAY DECOMPOSE ON
PRLNGD CONT W/LIGHT.
Disposal
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.